Design Strategies Research Articles

학급긍정훈육법을 활용한 초등 교육과정 연계 인성교육 프로그램 개발

Objectives The purpose of this study is to develop a character education program linked to the elementary school curriculum using positive classroom discipline. Methods The research method used to conduct this study was the ADDIE model, a representative ISD model. A design strategy was derived through requirements analysis such as literature analysis, case analysis, and expert interviews, and a draft of the program based on the design strategy was developed. An expert formative evaluation was conducted using FGI. Based on the results of the expert formative evaluation the program was modified and supplemented to produce the final version of the program. The final version of the program was verified for validity in five categories. Results The results of this study are as follows. First, a program design strategy was derived through literature analysis, case analysis, and needs analysis. Second, based on the program design strategy, a draft character edu-cation program using PDC was designed. Third, the final version of the program was derived through expert for-mative evaluation of the draft program. Fourth, as a result of verifying the program with a feasibility test tool, it was overall evaluated positively that the character education program using PDC had explanatory power, usefulness, validity, understanding, and universality. Conclusions As a result of the above research, it is expected that the character education program linked to the elementary curriculum using PDC developed in this study will be a useful program that can be used immediately by teachers in elementary schools. However, since this program consists of content suitable for use in upper grades, it is necessary to develop a program for lower grades of elementary school with easier questions and activities.

Ionic Hydrogen Bond-Assisted Catalytic Construction of Nitrogen Stereogenic Center via Formal Desymmetrization of Remote Diols.

The control of noncarbon stereogenic centers is of profound importance owing to their enormous interest in bioactive compounds and chiral catalyst or ligand design for enantioselective synthesis. Despite various elegant approaches have been achieved for construction of S-, P-, Si- and B-stereocenters over the past decades, the catalyst-controlled strategies to govern the formation of N-stereogenic compounds have garnered less attention. Here, we disclose the first organocatalytic approach for efficient access to a wide range of nitrogen-stereogenic compounds through a desymmetrization approach. Intriguingly, the pro-chiral remote diols, which are previously not well addressed with enantiocontrol, are well differentiated by potent chiral carbene-bound acyl azolium intermediates. Preliminary studies shed insights on the critical importance of the ionic hydrogen bond (IHB) formed between the dimer aggregate of diols to afford the chiral N-oxide products that feature a tetrahedral nitrogen as the sole stereogenic element with good yields and excellent enantioselectivities. Notably, the chiral N-oxide products could offer an attractive strategy for chiral ligand design and discovery of potential antibacterial agrochemicals.

Diversifying Ion-Transport Pathways of Composite Solid Electrolytes for High-Performance Solid-State Lithium-Metal Batteries.

The application of composite solid electrolytes (CSEs) in solid-state lithium-metal batteries is limited by the unsatisfactory ionic conductivity underpinned by the low concentration of free lithium ions. Herein, we propose an interface design strategy where an amine silane linker is employed as a coupling agent to graft the Li7La3Zr2O12 (LLZO) ceramic nanofibers to the poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) polymer matrix to enhance their interaction. The hydrogen bonding between amino-functionalized LLZO (NH2@LLZO) and PVDF-HFP not only effectively induces a uniform incorporation of high-content nanofibers (50 wt %) into the polymer matrix but also furnishes sufficient continuous surfaces to weaken the complexation between PVDF-HFP and Li-ion carriers. Additionally, introduction of the hydrogen bond and Lewis acid-base interplay strengthens the interfacial interactions between NH2@LLZO and lithium salts that release more free lithium ions for efficient interfacial transport. The impact of the linker's structure on the dissociation capacity of lithium salts is systematically studied from the steric effect perspective, which affords insights into interface design. Conclusively, the composite solid electrolyte achieves a high ionic conductivity (5.8 × 10-4 S cm-1) by synergy of multiple transport channels at ceramic, polymer, and their interface, which effectively regulates the lithium deposition behavior in symmetric cells. The excellent compatibility of the electrolyte with both LiFePO4 and LiNi0.8Co0.1Mn0.1O2 cathodes also results in a long lifetime and a high rate capability for full cells.

Metal Organic Frameworks as Polysulfide Reaction Modulators for Lithium Sulfur Batteries: Advances and Perspectives.

Currently, lithium sulfur (Li-S) battery with high theoretical energy density has attracted great research interest. However, the diffusion and loss process of intermediate lithium polysulfide during charge-discharge hindered the application of the Li-S battery in modern life. To overcome this issue, metal organic frameworks (MOFs) and their composites have been regarded as effective additions to restrain the LiPS diffusion process for Li-S battery. Benefiting from the unique structure with rich active sites to adsorb LiPS and accelerate the LiPS redox, the Li-S batteries with MOFs modified exhibit superior electrochemical performance. Considering the rapid development of MOFs in Li-S battery, this review summarizes the recent studies of MOFs and their composites as the sulfur host materials, functional interlayer, separator coating layer, and separator/solid electrolyte for Li-S batteries in detail. In addition, the promising design strategies of functional MOF materials are proposed to improve the electrochemical performance of Li-S battery.

The Role of the Built Environment in Supporting Older Adults' Engagement: A Narrative Literature Review.

This literature review aimed to summarize the existing knowledge surrounding the role of the built environment in supporting older adults' physical and social engagement and identify opportunities for future research and design that facilitates older adults' engagement at multiple environmental scales: from interior spaces to neighborhoods. Physical environments can support or impede older adults' physical and social engagement: willful, motivated involvement in meaningful activity or occupation. Research shows that engagement is a core component of health and well-being and relates to positive health outcomes, including reduced disease risk, better mental health, and improved physical and cognitive function. Thus, designing supportive built environments for engagement can yield significant, positive health and well-being impacts. A systematized search of five databases, a hand search, and an iterative screening process identified 55 studies for inclusion in this review. Through inductive thematic analysis, this review summarizes findings regarding the built environment's role in physical and social engagement in older age and design strategies to facilitate engagement and support health and well-being. Evidence indicates that built environment characteristics can influence older people's physical and social engagement in homes, neighborhoods, and care settings. The thematic analysis of the included studies identified three key themes concerning the relationships of built environment characteristics to older adults' engagement across multiple environmental scales: connection, access, and security. Built environments influence older people's physical and social engagement, significantly affecting their health, well-being, abilities, and longevity. Numerous design strategies can support older adults' engagement, but more research is needed.

An ultra-wideband power amplifier designed through a bandwidth expansion strategy

Abstract A bandwidth expansion strategy for ultra-wideband power amplifiers (PAs) is presented in this letter by adopting a parallel impedance matching architecture. This design strategy can effectively reduce the impedance conversion ratio between the load and the target impedance of the PA, thereby providing a feasible solution for broadband impedance matching. Subsequently, a commercially available 10 W gallium nitride device and a two-stage Wilkinson power divider network are combined to achieve the verification of the proposed theory. The results of the measurement show that within the target frequency band of 0.9–3.9 GHz, 58.5–71.2% of the drain efficiency and 9.1–12 dB of gain can be achieved with a saturated output power of 39.1–42 dBm.

Exploring the Potential of Artificial Intelligence as a Facilitating Tool for Formulation Development in Fluidized Bed Processor: a Comprehensive Review.

This in-depth study looks into how artificial intelligence (AI) could be used to make formulation development easier in fluidized bed processes (FBP). FBP is complex and involves numerous variables, making optimization challenging. Various AI techniques have addressed this challenge, including machine learning, neural networks, genetic algorithms, and fuzzy logic. By integrating AI with experimental design, process modeling, and optimization strategies, intelligent systems for FBP can be developed. The advantages of AI in this context include improved process understanding, reduced time and cost, enhanced product quality, and robust formulation optimization. However, data availability, model interpretability, and regulatory compliance challenges must be addressed. Case studies demonstrate successful applications of AI in decision-making, process outcome prediction, and scale-up. AI can improve efficiency, quality, and cost-effectiveness in significant ways. Still, it is important to think carefully about data quality, how easy it is to understand, and how to follow the rules. Future research should focus on fully harnessing the potential of AI to advance formulation development in FBP.

An Alkyne-bridged Covalent Organic Framework Featuring Interactive Pockets for Bromine Capture.

The high degree of corrosivity and reactivity of bromine, which is released from various sources poses a serious threat to the environment. Moreover, its coexistence with iodine forming an equilibrium compound, iodine monobromide (IBr) necessitates the selective capture of bromine from halogen mixtures. The electrophilicity of halogens to π-electron rich structures enabled us to strategically design a covalent organic framework for halogen capture, featuring a defined pore environment with localized sorption sites. The higher capture capacity of bromine (4.6gg-1) over iodine by ~41% shows its potential in selective capture. Spectroscopic results uncovering the preferential interaction sites are supported by theoretical investigations. The alkyne bridge is a core functionality promoting the selectivity in capture by synergistic physisorption, rationalized by the higher orbital overlap of bromine due to its smaller atomic size as well as reversible chemical interactions. The slip stacking in the structure has further promoted this phenomenon by creating clusters of molecular interaction sites with bromine intercalated between the layers. The inclusion of unsaturated moieties, i.e. triple bonds and the complementary pore geometry offer a promising design strategy for the construction of porous materials for halogen capture.

MOFs-Based Materials with Confined Space: Opportunities and Challenges for Energy and Catalytic Conversion.

Metal-Organic Frameworks (MOFs) are a very promising material in the fields of energy and catalysis due to their rich active sites, tunable pore size, structural adaptability, and high specific surface area. The concepts of "carbon peak" and "carbon neutrality" have opened up huge development opportunities in the fields of energy storage, energy conversion, and catalysis, and have made significant progress and breakthroughs. In recent years, people have shown great interest in the development of MOFs materials and their applications in the above research fields. This review introduces the design strategies and latest progress of MOFs are included based on their structures such as core-shell, yolk-shell, multi-shelled, sandwich structures, unique crystal surface exposures, and MOF-derived nanomaterials in detail. This work comprehensively and systematically reviews the applications of MOF-based materials in energy and catalysis and reviews the research progress of MOF materials for atmospheric water harvesting, seawater uranium extraction, and triboelectric nanogenerators. Finally, this review looks forward to the challenges and opportunities of controlling the synthesis of MOFs through low-cost, improved conductivity, high-temperature heat resistance, and integration with machine learning. This review provides useful references for promoting the application of MOFs-based materials in the aforementioned fields.

An Alkyne‐bridged Covalent Organic Framework Featuring Interactive Pockets for Bromine Capture

The high degree of corrosivity and reactivity of bromine, which is released from various sources poses a serious threat to the environment. Moreover, its coexistence with iodine forming an equilibrium compound, iodine monobromide (IBr) necessitates the selective capture of bromine from halogen mixtures. The electrophilicity of halogens to π‐electron rich structures enabled us to strategically design a covalent organic framework for halogen capture, featuring a defined pore environment with localized sorption sites. The higher capture capacity of bromine (4.6 g g‐1) over iodine by ~41 % shows its potential in selective capture. Spectroscopic results uncovering the preferential interaction sites are supported by theoretical investigations. The alkyne bridge is a core functionality promoting the selectivity in capture by synergistic physisorption, rationalized by the higher orbital overlap of bromine due to its smaller atomic size as well as reversible chemical interactions. The slip stacking in the structure has further promoted this phenomenon by creating clusters of molecular interaction sites with bromine intercalated between the layers. The inclusion of unsaturated moieties, i.e. triple bonds and the complementary pore geometry offer a promising design strategy for the construction of porous materials for halogen capture.

Evaluation of plastic hinge length in RC shear wall connected with floor slabs

Traditionally, seismic design focuses on inelastic behavior at the base of isolated shear walls. Yet, in multistoried RC wall-frame buildings with interconnected shear walls and floor slabs, significant inelasticity occurs at wall-slab junctions. This interaction greatly enhances the structure's seismic capacity. Previous studies overlooked this interaction, concentrating instead on isolated walls. The extent of inelastic action in a wall connected with floor slabs has not been studied extensively in the past. In the present study, the extent of the zone of inelastic behavior is studied at the wall-slab junction region by carrying out displacement based nonlinear static analysis of the wall-slab assemblages under monotonic as well as cyclic loads. A parametric study is carried out by varying the wall panel aspect ratio and axial load on walls. It is observed that this interaction using nonlinear static analysis, revealing increased curvature demand and localized damages at the junctions. It is observed that the extent of tensile damage at the junction region remains consistent across different axial load levels at the maximum drift level. Analytical expressions for plastic hinge length are proposed, crucial for refining seismic design strategies. The plastic hinge equation derived from pushover analysis yields values approximately 1.34 times higher than those obtained from cyclic loading.

Using the perceptions of online university students to improve the pedagogy and practice of distance educators

This paper reports on the findings of an investigation into the experiences of undergraduate and postgraduate distance education students from one higher education institution, Avondale College of Higher Education. All of the institution’s current students who were enrolled in a distance course or who had previously completed a distance component of their course were surveyed using an online questionnaire. A subgroup of this population also contributed to focus group discussions. Findings from an analysis of the combined data gathered from the online questionnaire and the focus groups were used to inform the institution’s professional development (PD) program that supports lecturers to design and teach online courses. Results of the study are outlined in terms of distance students’ perceptions about the institution’s distance education program, specifically in relation to course structure, interaction and communication, presentation of materials, use of media and design consistency. The paper concludes with recommendations for addressing the weaknesses of online learning programs including both curriculum design and PD strategies.

Stable Electron Spin Pan on Aromatic Oxalic Acid Radical

Comprehensive SummaryThe stability of organic radicals in ambient condition is important for their practical application. During the development of organic radical chemistry, the electron‐withdrawing and steric hindrance groups are usually introduced to improve the stability of radicals via reducing the reactivity of radicals with oxygen in air. Herein, the electron‐withdrawing carbonyl groups are introduced to construct a planar aromatic oxalic acid radical (IDF‐O8) with two‐dimensional electron spin pan structure. Interestingly, IDF‐O8 exhibited a low optical bandgap of 0.91 eV in film, however, the multiple quinone resonance structures between electron‐withdrawing ketone and phenol radicals contribute to the high stability of open‐shell radical IDF‐O8 without protection of large steric hindrance groups. Under the irradiation of 808 nm (1.2 W·cm–2), IDF‐O8 reaches 147 °C in powder state. This work provides an efficient synthesis route for the open‐shell electron spin pan system, which is different from the famous fullerene, carbon nanotube and graphene. The electron spin pan can be extended to spin tube or spin sphere system based on the design strategy of aromatic inorganic acid radicals in future.

Analysis Seismic Behavior of Structures with Planar Imperfections: A Comprehensive Numerical Analysis

This paper presents a comprehensive approach to the seismic analysis and design of a tall hospital building, accounting for horizontal irregularities and employing equivalent static analysis (ESA) methodology. The study initiates with the collection of relevant site data and building specifications, including the identification and characterization of horizontal irregularities such as setbacks, mass distribution variations, and irregular floor plans. Equivalent static lateral loads are calculated based on applicable building codes and standards, taking into account the effects of horizontal irregularities on seismic response. Structural modeling and analysis are then conducted using sophisticated software to evaluate the building's behavior under seismic forces, considering the influence of irregularities on structural performance. Design criteria, encompassing drift limits, strength requirements, and detailing considerations for mitigating irregularity effects, are rigorously adhered to ensure compliance with safety regulations and performance objectives. The iterative process of evaluation and adjustment ensures optimal seismic performance and adherence to design criteria despite the presence of horizontal irregularities. Documentation of the analysis and design process, coupled with meticulous construction oversight, guarantees the implementation of a robust seismic design strategy tailored to the unique characteristics of the tall hospital building. Post-construction evaluations are carried out to validate predicted seismic performance, accounting for the influence of horizontal irregularities. Through collaborative efforts and adherence to best practices, the seismic design of the tall hospital building prioritizes safety and resilience, even in the face of horizontal irregularities, aiming to safeguard occupants and critical healthcare infrastructure during seismic events.

Seismic and Wind Resillence Study of a 15 Story High-Rise Building with Floating Columns in Seismic Zones II & V

The use of floating columns in the construction of high-rise buildings, specifically in the context of G+15 structures in metropolitan cities, as per Indian standards. The structural design of a building is crucial for its durability, strength, stability, and lifespan. Floating columns play a significant role in transferring loads from the floors to the beams, affecting the overall stability of the building.Several factors impact the structural design, including bending moments, shear forces, torsion, and deflection. Due to the growing population in metropolitan areas, there is a need for high-rise buildings that can accommodate both commercial and residential spaces on a single platform. Commercial and residential floors have different load requirements. Therefore, floating columns are specifically used for residential floors to address these varying load demands. The structural analysis considers seismic and wind forces as per Indian standards (IS 1893-2016 for seismic analysis and IS 875-2015 for wind analysis) for different seismic zones (Zone- Ⅱ, Ⅲ, Ⅳ, and Ⅴ). The materials used in the construction include concrete with a grade of M40 and steel with a grade of Fe550. These material grades are commonly used in construction for their respective strength properties. The floor height for residential floors is 3 meters, while commercial floors have a height of 4 meters. This distinction in floor height is considered in the structural design. The design of high-rise buildings, especially in seismic-prone regions, requires a thorough understanding of structural engineering principles and adherence to local building codes and standards to ensure the safety and stability of the structure. The use of floating columns can be a part of a structural design strategy to address varying load requirements in different parts of the building.Safety is paramount in the design and construction of high-rise buildings, particularly in areas susceptible to seismic activity and strong winds.

Polyurethane-Encapsulated Biomass Films Based on MXene@Loofah Sponge for Piezoresistive Pressure Sensor Applications

Multifunctional wearable electronic sensors exhibit significant potential for applications in health management, motion tracking, intelligent healthcare, etc. In this study, we developed a novel assembly method for a polymeric silver nanowire (Ag NW)/transition metal carbide/nitride (MXene) @Loofah device using a facile solution dip-coating technique. During the pretreatment phase, the loofah was conditioned with polydiallyldimethylammonium chloride (PDAC), promoting the self-assembly of MXene layers and bolstering device stability. Then, the Ag NWs/MXene@Loofah was packaged with polyurethane to form a piezoresistive pressure sensor, which demonstrated superior pressure-sensing capabilities and was adept at registering movements of human joints and even subtle pulses. The design strategy presents a novel and rational approach to developing efficient pressure sensors.

Near-Infrared Absorbing Aza-BODIPY Dyes for Optoelectronic Applications.

Organic dyes that absorb light in the visible to near-infrared region have garnered significant interest, owing to their extensive utility in organic photovoltaics and various biomedical applications. Aza-boron-dipyrromethene (Aza-BODIPY) dyes are a class of chromophores with impressive photophysical properties such as tunable absorption from the visible region towards near infrared (NIR) region, high molar absorptivity, and fluorescence quantum yield. In this review, we discuss the developments in the aza-BODIPYs, related to their synthetic routes, photophysical properties and their applications. Their design strategies, modifications in chemical structures, mode/position of attachment, and their impact on photo-physical properties are reviewed. The potential applications of aza-BODIPY derivatives such as organic solar cells, photodynamic therapy, boron-neutron capture therapy, fluorescence sensors, photo-redox catalysis, photoacoustic probes and optoelectronic devices are explained.

A novel locally resonance metamaterial cylindrical shell with tower-shaped lattice for broadband vibration suppression

Vibration issues in cylindrical shells are prevalent in engineering applications and can significantly impact the operational performance of systems. To address these challenges, this paper designs a novel local resonance tower structure, and establishes an analytical model to investigate vibration characteristics of the metamaterial cylindrical shell. Based on the model, a gradient design strategy is proposed to improve vibration suppression properties over a wide frequency range. Firstly, the governing equations of the cylindrical shell are derived and the dispersion analysis is conducted to predict the bandgap boundaries using the extended plane wave expansion (EPWE) method. Then, for a finite-period metamaterial cylindrical shell with specific boundary conditions, the frequency response of the structure is obtained by finite element calculations to show the bandgap behavior. The results of these two methods are basically the same. In addition, the effects of frequency spacing, damping and array period on the vibration characteristics are considered comprehensively. The results show that a wider and more stable attenuation range can be obtained by reasonably adjusting these three parameters. Finally, the comparison between experimental and numerical calculations verify that the tower structure is effective, and that the proposed design strategy can broaden the vibration attenuation region.

Design and Development of an Air–Land Amphibious Inspection Drone for Fusion Reactor

This paper proposes a design method for a miniature air–land amphibious inspection drone (AAID) to be used in the latest compact fusion reactor discharge gap observation mission. Utilizing the amphibious function, the AAID realizes the function of crawling transportation in the narrow maintenance channel and flying observation inside the fusion reactor. To realize miniaturization, the mobile platform adopts the bionic cockroach wheel-legged system to improve the obstacle-crossing ability. The flight platform adopts an integrated rotor structure with frame and control to reduce the overall weight of the AAID. Based on the AAID dynamic model and the optimal control method, the control strategies under flight mode, hover mode and fly–crawl transition are designed, respectively. Finally, the prototype of the AAID is established, and the crawling, hovering, and fly–crawling transition control experiments are carried out, respectively. The test results show that the maximum crawling inclination of the AAID is more than 20°. The roll angle, pitch angle, and yaw angle deviation of the AAID during hovering are all less than 2°. The landing success rate of the AAID during the fly–crawl transition phase also exceeded 77%, proving the effectiveness of the structural design and dynamic control strategy.

Exploring Generative Adversarial Networks for Face Generation

This research has used Generative Adversarial Networks (GANs) for face generation in the area of the research [1]. GANs have demonstrated a high effectiveness in imitation of natural images not only, but also in specific applications [2]. For the succeeding paper, their potential especially on creating human faces are being looked into. The primary goal is to develop a new design and practical training strategy to efficiently produce high-quality facial images [3]. Experimental results confirm the ability of the proposed method to generate artificially intelligent faces and its role in improving the quality of the images.